PPSC Lecturer Chemistry Past Paper Dated: 2015

61- A gas has a volume of 2 liters at STP at constant pressure. The new volume is 4 liters at which temperature?

A. 0°C
B. 50°C
C. 100°C
D. 273°C

Answer : D. 273°C

62- The difference between crystalloids and colloids is:

A. Density
B. Solubility
C. Color
D. Particle size

Answer : D. Particle size

63- The gas which shows deviation from ideal behavior is:

A. Helium
B. Hydrogen
C. Ammonia
D. Trichloromethane

Answer : C. Ammonia

64- A substance shows scattering of light but can pass through ordinary filter paper. It is:

A. Colloids
B. Suspension
C. True solution
D. None of these

Answer : A. Colloids

65- In the lime kiln, CaCO₃ → CaO + CO₂ proceeds to completion because:

A. CO₂ escapes
B. CaO is removed
C. Low temperature
D. High pressure

Answer : A. CO₂ escapes

66- Which equation is NOT affected by change in pressure?

A. ½N₂ + ½O₂ → NO
B. P₂O₅ → P₂O + O₂
C. N₂ + 3H₂ → 2NH₃
D. None of these

Answer : A. ½N₂ + ½O₂ → NO

67- A reaction approaches farthest completion when:

A. K = 10²
B. K = 10¹
C. K = 10⁰
D. K = 10⁻²

Answer : A. K = 10²

68- An isothermal system is one in which:

A. V = 0
B. E = 0
C. ΔT = 0 
D. ΔE = W

Answer : C. ΔT = 0

69- Temperature of the system decreases in:

A. Adiabatic expansion
B. Adiabatic compression
C. Isothermal expansion
D. Isothermal compression

Answer : A. Adiabatic expansion

70- A system in which no change in temperature occurs is:

A. Isochoric
B. Isobaric
C. Isothermal
D. Adiabatic

Answer : C. Isothermal

71- The cyclic structure of benzene was given by:

A. Kekulé
B. Dobereiner
C. Newlands
D. Mendeleev

Answer : A. Kekulé

72- Which is least soluble in water?

A. Ethanol
B. Benzene
C. Benzoic acid
D. Phenol

Answer : B. Benzene

73- Heterogeneous catalysis is based on:

A. Desorption
B. Sorption
C. Absorption
D. Adsorption

Answer : D. Adsorption

74- The entropy of the universe is:

A. Always increasing
B. Always decreasing
C. Constant
D. Zero

Answer : A. Always increasing

75- Which indicator is NOT used in a conical flask?

A. Self indicator
B. External indicator
C. Internal indicator
D. Mixed indicator

Answer : B. External indicator

76- Toluene is prepared from benzene by:

A. Wurtz reaction
B. Cannizzaro reaction
C. Perkin reaction
D. Friedel-Crafts alkylation

Answer : D. Friedel-Crafts alkylation

77- The catalyst used in Friedel-Crafts alkylation is:

A. BF₃
B. AlCl₃
C. FeCl₃
D. ZnCl₂

Answer : B. AlCl₃

78- The order of a reaction is:

A. Always 1
B. Always 2
C. Can be determined from the equation
D. Can be determined from experiment

Answer : D. Can be determined from experiment

79- The oxidation number of P in KH₂PO₂ is:

A. +1
B. +2
C. +3
D. +5

Answer : A. +1

80- Molten KCl conducts electricity because of:

A. Free ions
B. Free electrons
C. Both A and B
D. None of these

Answer : A. Free ions

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