Sindh MDCAT 2019 Paper

121- The colour of transition metal complexes is due to:

A. d-d transition of electrons
B. Paramagnetic nature of transition elements
C. Loss of s-electrons
D. Refraction phenomenon  

Answer : A. d-d transition of electrons

122- Determine the significant figures in 0.0085:

A. 1
B. 2
C. 3
D. 4

Answer : B. 2

123- Orbitals having same energy are called:

A. Hybrid orbitals
B. Degenerate orbitals
C. Valence orbitals
D. Sub-orbitals

Answer : B. Degenerate orbitals

125- Copper (Cu, Z=29) is a:

A. d’ system with respect to electronic configuration  
B. d’ system with respect to electronic configuration
C. d’ system with respect to electronic configuration
D. d¹⁰ system with respect to electronic configuration

Answer : D. d¹⁰ system with respect to electronic configuration

126- The carbon number of gasoline is:

A. C5 – C6
B. C6 – C7 
C. C5 – C10
D. C12 – C15

Answer : C. C5 - C10

127- The oxidation number of Br- in Br2 is:

A. -2
B. -1
C. 0
D. +1  

Answer : C. 0

128- The number of moles of CO2 which contain 8.0 g of oxygen is:

A. 0.25
B. 0.50
C. 0.75
D. 1.0

Answer : A. 0.25

129- Hydrogen bonds are represented by:

A. dative bonds
B. full bond
C. partial charges
D. dotted bonds

Answer : D. dotted bonds

130- Effusion of gases take place through a hole with:

A. Hole dimensions 
B. Infinite dimensions
C. Slit like dimensions
D. Molecular dimensions

Answer : D. Molecular dimensions

131- The units of Ksp for the following reaction are: PbCl2 (g) ⇔ Pb+2+ 2Cl-(g)

A. mol⁸ dm-⁹  
B. mol dm-⁶  
C. mol⁷ dm-⁵  
D. mol dm-⁹

Answer : A. mol⁸ dm-⁹

132- In t-butyl alcohol, the tertiary carbon is bonded to:

A. No H-atoms
B. One H-atoms
C. Three H-atoms
D. Four C-atoms

Answer : A. No H-atoms

133- The standard reduction potential of hydrogen electrode is:

A. -0.76 volts
B. 0.00 volts
C. +1.5 volts
D. 1.0 volts

Answer : B. 0.00 volts

134- Down's cell is used to prepare:

A. Sodium carbonate
B. Sodium bicarbonate  
C. Sodium hydroxide
D. Sodium metal

Answer : D. Sodium metal

135- Which of the hydrogen compounds has the highest percentage of ionic character?

A. HCl
B. HBr
C. HI
D. HF

Answer : D. HF

136- Quantum number values for 2p orbitals are:

A. n=2 l=1
B. n=2 l=2 
C. n=2 l=0 
D. n=1 l=0  

Answer : A. n=2 l=1

137- Solubility product of AgCl is 2.0x10^-10 mol^-4 dm^-6. Maximum concentration of Ag^+ ions in the solution is:

A. 2.0×10^-12 mol dm^-3
B. 1.4×10^-12 mol dm^-3  
C. 1.0×10^-12 mol dm^-3  
D. 2.5×10^-10 mol dm^-3  

Answer : D. 2.5x10^-10 mol dm^-3

138- A limiting reactant is the one, which:

A. is taken in lesser quantity in grams as compared to the other reactant
B. Is taken in lesser quantity in volume as compared to the other reactant  
C. gives the minimum amount of the product which is required
D. gives equal amount of the reactants and products  

Answer : C. gives the minimum amount of the product which is required

139- The chemical formula of Tincal is:

A. Na_2B_4O_7·10H_2O
B. Na_2B_4O_7·10H_2O
C. Na_2B_4O_7·H_2O
D. Na_2B_4O_5·10H_2O

Answer : A. Na_2B_4O_7·10H_2O

140- Hydrogen resembles with the elements of groups:

A. I-A, V-A and VIII-A  
B. I-A, IV-A and VI-A
C. I-A, II-A and VII-A
D. I-A, IV-A and VII-A

Answer : D. I-A, IV-A and VII-A

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