Sindh MDCAT 2020 Paper

101- The transition element which does not show variable valency is:

A. Cu
B. Sc
C. Zn
D. Cr

Answer : C. Zn

102- Select the organic compound which belongs to Arene family:

A. CH2=CH2
B. CH3-O-CH3
C. CH3-NH2
D. C6H6

Answer : D. C6H6

103- The type of isomerism existing in a compound of molecular formula C2H6O is:

A. Functional group
B. Position
C. Chain
D. Metamerism

Answer : A. Functional group

105- General formula of cycloalkane is?

A. CnH2n+2
B. CnH2n
C. CnH2n+1
D. CnH2n-2

Answer : B. CnH2n

106- Electrophile in sulphonation of benzene is:

A. HSO4-  
B. H2SO4
C. SO3
D. HSO3-  

Answer : C. SO3

108- Acetonbenone can be formed by which of the following reaction of benzene?

A. Alkylation
B. Acylation
C. Halogenation
D. Nitration

Answer : B. Acylation

109- In alkanes, each Carbon has hybridization:

A. sp³
B. sp
C. sp²
D. dsp

Answer : A. sp³

110- When CH₃ is attached with the benzene ring, it makes the ring:

A. Good electrophile
B. Good nucleophile
C. Resonance hybrid  
D. Extraordinary stable

Answer : B. Good nucleophile

111- Which of the following reaction has greater Kp than Kc (Kp > Kc)?

A. 2NO + Cl₂ = 2NOCl  
B. 2SO2 + O₂ = 2SO3 
C. 2NOCl = 2NO + Cl₂
D. NO2 + 3H2 = 2NH3  

Answer : C. 2NOCl = 2NO + Cl₂

112- The equation N2g + 3H2g = 2NH3, represents:

A. Haber’s process
B. Contact process
C. Solvay process
D. Avogadro’s law

Answer : A. Haber's process

113- The unit of the rate constant is the same as that of the rate of reaction in:

A. Zero order reaction
B. First order reaction
C. Second order reaction
D. Third order reaction  

Answer : B. First order reaction

114- The study of rates of chemical reactions and the factors that affect the rates of chemical reactions is known as:

A. Thermodynamics
B. Stoichiometry
C. Electrochemistry
D. Chemical kinetics

Answer : A. Thermodynamics

115- For the reaction A(g) → products, When the concentration of A(g) doubles, the rate of reaction increases four folds, which means it is:

A. Negative order reaction
B. First order reaction
C. Zero order reaction
D. Second order reaction

Answer : D. Second order reaction

116- For which of the following order of the reaction, rate of reaction is inversely proportional to the concentration of reaction?

A. 1st order reaction
B. 2nd order reaction
C. Negative order of reaction
D. Zero order of reaction

Answer : C. Negative order of reaction

117- The thermal energy at constant pressure is called:

A. Enthalpy
B. Internal energy
C. Heat capacity 
D. Work done 

Answer : A. Enthalpy

118- Born-Haber cycle is used to determine the lattice energies of:

A. Molecular solids
B. Metallic solids
C. Ionic solids
D. Covalent solids

Answer : C. Ionic solids

119- One calorie is equal to:

A. 4.18 KJ
B. 4.18 J
C. 0.418 KJ mol 
D. 0.418 KJ

Answer : B. 4.18 J

120- The oxidation state of 'S' in the (S2O3)-2 is:

A. +4
B. +6
C. -2
D. +2

Answer : D. +2

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