ETEA MDCAT Past Paper 2024

81- The unit of Kc for the system PCl₅ = PCl₃ + Cl₂ is?

A. dm³/mol
B. mol/dm³
C. mol/dm⁶
D. mol²/dm⁶

Answer : B. mol/dm³

82- For a first order reaction A → B, the rate constant is 0.0458 s⁻¹. Calculate rate of the reaction if the concentration of reactant is 0.35mol dm⁻³.

A. 0.012 mol dm⁻³ s⁻¹
B. 0.014 mol dm⁻³ s⁻¹
C. 0.016 mol dm⁻³ s⁻¹
D. 0.018 mol dm⁻³ s⁻¹

Answer : C. 0.016 mol dm⁻³ s⁻¹

83- A reaction is first order with respect to A and second order with respect to B, the rate equation is?

A. Rate = k [A]
B. Rate = k [A][B]
C. Rate = k [A]²[B]
D. Rate = k [A][B]²

Answer : D. Rate = k [A][B]²

84- What mass of aluminium oxide (Al₂O₃) is produced from 18.5g of Al metal, when it reacts completely with oxygen gas according to the following equation?
4Al(s) + 3O₂(g) → 2Al₂O₃(s)

A. 30.8g
B. 32.6g
C. 34.9g
D. 36.5g

Answer : C. 34.9g

85- Calculate the work done when 1 mole of an ideal gas expands from 15 dm³ to 20 dm³ against a constant external pressure of 2 atmospheres.

A. -10 atm.dm³
B. -5 atm.dm³
C. 5 atm.dm³
D. 10 atm.dm³

Answer : A. -10 atm.dm³

86- When 1 mole of ice melts at 0°C and constant pressure of 1 atmosphere, 6025 J of heat is absorbed by the system. The molar volume of ice and water are 0.020 and 0.018 dm³, respectively. Calculate ΔE. (1dm³.atm=101.33J)

A. 6010.20J
B. 6015.20J
C. 6020.20J
D. 6025.20J

Answer : A. 6010.20J

87- One slice of bread with a tablespoon of peanut butter on it contains 20g carbohydrate, 10g protein, and 9g fat. Calculate total energy consumed in this intake.

A. 158kcal
B. 173kcal
C. 201kcal
D. 218kcal

Answer : C. 201kcal

88- ΔH can be measured indirectly by applying?

A. Avogadro’s law
B. Faraday’s law
C. Gas’s law
D. Hess’s law

Answer : D. Hess’s law

89- The heat of sublimation of potassium is 98kJ/mol, the heat of dissociation of bromine gas is 192.5 kJ/mol. The ionization energy of K is 414 kJ/mol. The electron affinity of Br is -334.7 kJ/mol and the heat of formation of KBr is -405.8 kJ/mol. Calculate the lattice energy of KBr.

A. -679.3
B. -669.5
C. 669.5
D. 679.3

Answer : D. 679.3

90- Which one of the following is a strong electrolyte in solution?

A. Acetic acid
B. Ammonium hydroxide
C. Carbonic acid
D. Potassium iodide

Answer : D. Potassium iodide

91- When 4 g of magnesium was heated in excess of oxygen. Calculate the theoretical yield of magnesium oxide (MgO).

A. 3.7g
B. 4.2g
C. 5.4g
D. 6.6g

Answer : D. 6.6g

92- The electrode potential of the standard hydrogen electrode is chosen as:

A. -1 V
B. 0 V
C. 1 V
D. 2 V

Answer : B. 0 V

93- Electromegativity of Al is approximately equal to that of?

A. B
B. Be
C. Mg
D. Na

Answer : B. Be

94- Which of the following alkali metal forms only normal oxide with O₂?

A. K
B. Li
C. Na
D. Rb

Answer : B. Li

95- Third period element that initially reacts rapidly with oxygen to form a protective oxide coating that prevents further reactions is:

A. Al
B. Mg
C. Na
D. Si

Answer : A. Al

96- Cu²⁺ salt solution is blue in colour due to transition of electrons from?

A. d to d orbital
B. p to d orbital
C. p to p orbital
D. s to p orbital

Answer : A. d to d orbital

97- Potassium ferrocyanide is which type of salt?

A. Complex
B. Double
C. Mixed
D. Normal

Answer : A. Complex

98- Name of ketone functional group is?

A. Amino
B. Carbonyl
C. Carboxyl
D. Formyl

Answer : B. Carbonyl

99- Pyridine belongs to which class of organic compounds?

A. Alicyclic
B. Heterocyclic
C. Homocyclic
D. Hydrocarbon

Answer : B. Heterocyclic

100- Which of the following elements cannot be detected directly in a given organic compound?

A. Chlorine
B. Nitrogen
C. Oxygen
D. Phosphorous

Answer : C. Oxygen

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